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From WoWWiki's entry on Blacksmithing:
Becoming a Weaponsmith Becoming an Artisan Weaponsmith gives you access to a number of plans for new weapons. You need to be level 40 with a blacksmithing skill level of 200. The path to become an Weaponsmith is similar for both Alliance blacksmiths and Horde Blacksmiths.
Smiths will need to first talk to their respective representative.
A-Myolor Sunderfury in Ironforge
H-Krathok Moltenfist in Orgrimmar
The representative will then direct them to another person who will direct you to speak to either the Master Armorsmith or the Master Weaponsmith. The Master Weaponsmiths are:
A-Ironus Coldsteel in Ironforge
H-Borgosh Corebender in Orgrimmar
The Master Weaponsmith will now give you the quest "The Way of the Weaponsmith" (Alliance Version, Horde Version) which will require you to craft 4 [Moonsteel Broadsword]s, 4 [Massive Iron Axe]s, 2 [Heavy Mithril Axe]s, and 2 [Big Black Mace]s. The plans for the Moonsteel Broadsword and the Massive Iron Axe are Limited Sale Recipes and may be difficult to get. The other two plans are available from the trainer.
Turn in all the crafted weapons to the Master Weaponsmith to become a Weaponsmith!
The complete list of materials required to craft all the weapon pieces required to become an Weaponsmith is:
[Iron Bar] x 56
[Steel Bar] x 32
[Mithril Bar] x 56
[Gold Bar] x 16
[Strong Flux] x 16
[Heavy Grinding Stone] x 16
[Solid Grinding Stone] x 4
[Heavy Leather] x 28
[Thick Leather] x 4
[Shadowgem] x 8
[Lesser Moonstone] x 12
[Citrine] x 4
[Black Pearl] x 2
If you wish to specialize even further in Weaponsmithing, you can become an Axesmith, Hammersmith, or a Swordsmith. You must be level 50 with a blacksmithing skill level of 250 with the Weaponsmithing specialty. The subspecialties are taught by trainers in Everlook, Winterspring. There is no cost to learn a Weaponsmithing subspeciality and it does not require a quest. The three trainers are:
Axesmithing - Kilram
Hammersmithing - Lilith the Lithe
Swordsmithing - Seril Scourgebane